Switching molecular recognition selectivities by temperature in a diffusion-regulatory porous material.
Su Y, Otake KI, Zheng JJ, Xu H, Wang Q, Liu H, Huang F, Wang P, Kitagawa S, Gu C.
Su Y, et al.
Nat Commun. 2024 Jan 2;15(1):144. doi: 10.1038/s41467-023-44424-3.
Nat Commun. 2024.
PMID: 38168057
Free PMC article.
Herein, we report temperature-responsive recognition of two similar gaseous guests, CO(2) and C(2)H(2), with selectivities switched by temperature change by a diffusion-regulatory mechanism, which is realized by a dynamic porous crystal featuring ultrasmall pore apertures with …
Herein, we report temperature-responsive recognition of two similar gaseous guests, CO(2) and C(2)H(2), with selectivities switched by tempe …